I think any more than a 10 minutes drive will heat up the tyres to a point that the pressure will be inaccurate from cold tyre pressure. Try to do it in the morning.
The higher the pressure, the less side wall flex there is for the piece of rubber between the rim and the road. Imagine, if you were to take a piece of rubber and keep bending it back and forth for a few minutes. It is going to get hot. The same will apply to the tyres, as the rubber rolls under the rim, it bends under the weight of the vehicle, but once it rolls up and away, it bounces back to it's original shape. This is going to go on for hours at high speed resulting in fatigue of the material.
Units, I think you mean Kilo Pascals (kPa) and not Pounds per Square Inch (PSI)
The higher the pressure, the less side wall flex there is for the piece of rubber between the rim and the road. Imagine, if you were to take a piece of rubber and keep bending it back and forth for a few minutes. It is going to get hot. The same will apply to the tyres, as the rubber rolls under the rim, it bends under the weight of the vehicle, but once it rolls up and away, it bounces back to it's original shape. This is going to go on for hours at high speed resulting in fatigue of the material.
Units, I think you mean Kilo Pascals (kPa) and not Pounds per Square Inch (PSI)